Nitrocellulose-Based
Propellants

Propellant formulations combine a primary fuel and oxidizer with additives—such as plasticizers, stabilizers, burn-rate modifiers, and binders—to control performance and safety. These mixtures serve in small-arms and artillery ammunition, rocket motors, and civilian propellant applications, where additives act as stabilizers, ballistic modifiers, and plasticizers, and binders help form the solid matrix of the propellant.

Common applications include:

  • Small-caliber gunpowder

  • Single, double and triple-based ammunition propellants

  • Double-based rocket propellants

Nitrocellulose

Nitrocellulose is the commercial term for cellulose nitrate, the nitric ester of cellulose. It is obtained by esterification of cellulose and nitric acid.

Propellant Stabilizers for NC-Based Propellants

NC-based propellants are naturally unstable and gradually break down. They lose nitrogen oxides, and those released gases react with and damage the NC molecules, causing degradation.

To prevent NC degradation, stabilizers with a higher affinity for nitrogen oxides are incorporated; these stabilizers absorb the oxides before they can attack the nitrocellulose.

Stabilizer

Type

Specifiation

2,4-Dinitrotoluene (DNT)

Single-Base

MIL-D-204

2,4-Dinitrotoluene (DNT)

Single-Base

MIL-D-204

2-Nitrodiphenylamine (2-NDPA)

Double-Base

MIL-N-3399

2-Nitrodiphenylamine (2-NDPA)

Double-Base

MIL-N-3399

Akardite II

Multi-Base

DOD-M-64040

Akardite II

Multi-Base

DOD-M-64040

Diphenylamine (DPA)

Single-Base

MIL-D-98

Diphenylamine (DPA)

Single-Base

MIL-D-98

Ethyl Centralite

Multi-Base

MIL-E-255

Ethyl Centralite

Multi-Base

MIL-E-255

Methyl Centralite

Multi-Base

MIL-M-19719

Methyl Centralite

Multi-Base

MIL-M-19719

N-Methyl-p-Nitroaniline (MNA)

Solid Fuel

MIS-35107

N-Methyl-p-Nitroaniline (MNA)

Solid Fuel

MIS-35107

Nitrocellulose-Based Propellant Additives

Additive

Function

Specification

Carbon Black

Opacifier

Carbon Black

Opacifier

Di-Normal Propyl Adipate (DNPA)

Plasticizer

MIL-D-22346

Di-Normal Propyl Adipate (DNPA)

Plasticizer

MIL-D-22346

Diethyl Phthalate

Plasticizer

JAN-D-242

Diethyl Phthalate

Plasticizer

JAN-D-242

Graphite

Opacifier/Lubricant

MIL-G-155

Graphite

Opacifier/Lubricant

MIL-G-155

Oxamide

Coolant

MIL-O-60863

Oxamide

Coolant

MIL-O-60863

Potassium Nitrate (KNO3)

Flame Suppressant

MIL-E-255

Potassium Nitrate (KNO3)

Flame Suppressant

MIL-E-255

Potassium Sulfate (K2SO4)

Flame Suppressant

MIL-P-193

Potassium Sulfate (K2SO4)

Flame Suppressant

MIL-P-193

Triacetin (Glyceryl Triacetate)

Plasticizer

MIL-T-301

Triacetin (Glyceryl Triacetate)

Plasticizer

MIL-T-301

Zirconium Carbide (ZrC)

Combustion Instability Suppressant

MIL-Z-85500

Zirconium Carbide (ZrC)

Combustion Instability Suppressant

MIL-Z-85500

Ballistic Modifiers

Small additions of lead compounds to double-base rocket propellants result in an increased burn rate under low-pressure conditions.

Lead salts cause the burning rate to remain steady regardless of pressure or ignition temperature. A strong burn-rate/pressure relationship is beneficial because it enables lighter rocket motors through lower safety requirements.

Chemical Name

Specification

Copper Beta Resorcylate, Monobasic

Copper Beta Resorcylate, Monobasic

Copper Monobasic Salicylate

AS-323

Copper Monobasic Salicylate

AS-323

LC-12-0 to LC-12-20

LC-12-0 to LC-12-20

Lead 2-Ethyl Hexoate (Lead Octoate)

MIL-L-17699

Lead 2-Ethyl Hexoate (Lead Octoate)

MIL-L-17699

Lead Beta Resorcylate

AS-2853

Lead Beta Resorcylate

AS-2853

LC-12-15 Ballistic Modifier

MIL-B-85735

LC-12-15 Ballistic Modifier

MIL-B-85735

Lead Salicylate

MIL-L-13788, MIL-L-17700

Lead Salicylate

MIL-L-13788, MIL-L-17700

Lead Stearate

MIL-L-758A

Lead Stearate

MIL-L-758A